Unprecedented steric deformation of ortho-carborane.
نویسندگان
چکیده
The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities.
منابع مشابه
Isomerisation of nido-[C2B10H12]2– dianions: unprecedented rearrangements and new structural motifs in carborane cluster chemistry† †Electronic supplementary information (ESI) available: Movies of the 1,7 to 7,9 isomerisation (17-79_isom.avi), ortho-carborane reduction (ortho-carborane_RED.avi) and meta-carborane reduction (meta-carborane_RED.avi); alternative reaction profiles; computed Cartesian coordinates and energies for all structures. See DOI: 10.1039/c5sc00726g Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file.
Institute of Chemical Sciences, School Heriot-Watt University, Edinburgh, EH14 4 uk; Fax: +44 (0)1314513180; Tel: +44 (0)13 † Electronic supplementary information (E isomerisation (17-79_isom.avi), ortho-carbor and meta-carborane reduction (meta-ca proles; computed Cartesian coordinates a 10.1039/c5sc00726g ‡ Present address: School of Chemistry, S Andrews, Fife, KY16 9ST, UK. Cite this: Chem....
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ورودعنوان ژورنال:
- Chemical communications
دوره 42 شماره
صفحات -
تاریخ انتشار 2008